[JACS] 我室毛秉伟教授和田中群教授发表论文:Toward long-term stability: single crystal alloys of cesium-containing mixed cations and mixed halides perovskite

我室毛秉伟教授和田中群教授在 JACS 上发表论文:Toward long-term stability: single crystal alloys of cesium-containing mixed cations and mixed halides perovskite

文章链接:https://pubs.acs.org/doi/10.1021/jacs.8b11610

摘要:

Perovskite solar cells are strong competitor for silicon-based ones, but suffer from poor long-term stability for which the intrinsic stability of perovskite materials is of primary concern. Herein, we prepared a series of well-defined cesium-containing mixed cations and mixed halides perovskite single crystal alloys, which enabled systematic investigations on their structural stabilities against light, heat, water and oxygen. Two potential phase separation processes are evidenced for the alloys as cesium content increases to 10% and/or bromide to 15%. Eventually, a highly stable new composition, (FAPbI3)0.9(MAPbBr3)0.05(CsPbBr3)0.05 emerges with carrier lifetime of 16 μs. It maintains stable during at least 10,000 h water-oxygen and 1,000 h light stability tests, which is very promising for long-term stable devices with high efficiency. The mechanism for the enhanced stability is elucidated through detailed single crystal structure analysis. Our work provides a single crystal-based paradigm for stability investigation, leading to discovery of stable new perovskite materials.